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Lecture 16 - Abiotic Transformation in the Environment

See Lecture Schedule for Delivery Date

Learning Objectives

  1. Understand the role of solar photons as an energy source for chemical reactions in the environment.
  2. Describe, in general, the dynamics of excited states in producing products and photo-sensitized reactants.
  3. Understand the major abiotic chemical reaction pathways in the environment.
  4. Describe electrophillic, nucleophillic, hydrolysis and redox reactions.
  5. Summarize the basic reactions associated with the formation of the hole in the ozone layer.
  6. Summarize the reactions associated with the formation of acid rock drainage.

LECTURE MATERIALS

Slides

PDF Notes

LECTURE ACTIVITIES

Homework

Discussion

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Advanced Reading

  1. EPA: The Science of Ozone Layer Depletion
  2. OSMRE: Acid Mine Drainage

Resources

Keywords

  • Photochemical
  • Photolysis
  • Photoexcitation
  • Quantum yield
  • Energy level
  • Transition
  • Triplet state
  • Singlet state
  • Hydrolysis
  • Oxidant
  • Oxidation
  • Reduction
  • Free radical
  • Photodegradation
  • Redox potential
  • Pourbaix diagram
  • Electrophillic, electrophile
  • Nucleophillic, nucleophile
  • Ozone layer
  • Ozone hole
  • Acid rock drainage
  • Sulfate reducing bacteria
  • Sulfur oxidizing bacteria

Suggested Reading

  1. The Ozone Hole Tour
  2. The Ozone Hole, 2008 Data
  3. The Ozone Hole