Lecture 17 - Environmental Chemodynamics
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Learning Objectives
- List the thermodynamic functions used to describe the energy status of molecules in an environmental system.
- Understand the relationship of Gibb’s free energy and chemical potential in the transfer or transformation of chemicals in a system.
- Develop a basic understanding of fugacity and its role in environmental transformations.
- Define activity and its relationship to concentration.
- Understand the concept of energy bookkeeping and the relationship of Gibb’s free energy to enthalpy and entropy in an phase transformation or chemical reaction.
- Develop a basic understanding of first order and psuedo-first order chemical kinetics including integrated rate expressions, half-lives and T dependence.
- Understand the compartment model of the ecosphere.
- Understand the partitioning of chemicals and how partition constants are used in describing environmental systems.
- Understand the basic approaches to modeling chemodynamics and the usefulness and limitations of model use.