Publications

> 3200 citations, h ~ 25
60 Ghebreamlak S, Stoian SA; Lees N, Cronin B, Smith F, Ross M, Telser J, Hoffman B, Duin E The active-site [4Fe-4S] cluster in the isoprenoid biosynthesis enzyme IspH adopts unexpected redox states during ligand binding and catalysis. J. Am. Chem. Soc., 2024, 146, 3926-3942
59 Toubiana LA, Valaydon-Pillay A, Elinburg J, Bacon J, Ozarowski A, Doerrer L, Stoian SA Spectroscopic and Theoretical Investigation of High-Spin Square-Planar and Trigonal Fe(II) Complexes Supported by Fluorinated Alkoxides Inorg. Chem., 2024, 63, 2370-2387
58 Shisler KA, Kincannon WM, Mattice JR, Larson J, Valaydon-Pillay A, Mus F, Flusche T, Nath AK, Stoian SA, Raugei S, Bothner B, DuBois JL, Peters JW Homologous acetone carboxylases select Fe(II) or Mn(II) as the catalytic cofactor mBio, 2024, 15, e02987-23
57 Anderson MG, Trent MK, Idrees MZ, Stoian SA, McCandless GT, Baumbach RE, Chan JY Ironing Out the Transition Metal Contribution to the Magnetism of the n = 3 members of the Homologous Series Prn+1MnGe3n+1 (M = Fe,Co): Pr4Co3Ge10 vs. Pr4Co3Ge10 J. Alloys Compd., 2024, 976, 172974
56 Tener ZP, Yannello V, Garlea VO, Lapidus SH, Yox P, Kovnir K, Stoian SA, Shatruk M Evolution of Bonding and Magnetism via Changes in Valence Electron Count in CuFe2-xCoxGe2 Inorg. Chem., 2022, 61, 4257-4269
55 Stoian SA, Moshari M, Ferentinos E, Grigoropoulos A, Krzystek J, Telser J, Kyritsis P Electronic Structure of Tetrahedral, S = 2 [Fe{(EPiPr2)2N}2], E = S, Se Complexes: Investigation by High-Frequency and High-Field Electron Paramagnetic Resonance, 57Fe Mössbauer Spectroscopy, and Quantum Chemical Studies Inorg. Chem., 2021, 60, 10990-11005
54 Greer SM, Graminga KM, Thomas CM, Stoian SA, Hill S Insights into Molecular Magnetism in Metal-Metal Bonded Systems as Revealed by a Spectroscopic and Computational Analysis of Diiron Complexes Inorg. Chem., 2020, 59, 18141-18155
53 Hao L, Stoian SA, Weddle LR. Zhang Q Zr-based MOFs for oxidative desulfurization: What matters? Green Chemistry, 2020, 22, 6351-6356
52 Premuzic D, Hołyńska M, Ozarowski A, Pietzonka C, Roseborough A, Stoian SA Model Dimeric Manganese(IV) Complexes Featuring Terminal Tris-Hydroxotetraazaadamantane and Various Bridging Ligands Inorg. Chem., 2020, 59, 10768-10784
51 Kaniewska K; Ponikiewski Ł; Szynkiewicz N; Cieślik B; Pikies J; Krzystek J; Dragulescu-Andrasi A; Stoian SA; Grubba R Homoleptic mono-, di-, and tetra-iron complexes featuring phosphido ligands: a synthetic, structural, and spectroscopic study Dalton. Trans., 2020, 49, 2020
50 Fleming C, Chung D, Ponce S, Das R, Brook DJR, daRos J, Ozarowski A, Stoian SA Valence Tautomerism in Cobalt-Verdazyl Coordination Compound

Inside Cover

Chem. Comm., 2020, 56, 4400
49 Roseborough A,Wheeler KA, Hołyńska H, Stoian SA Synthesis and Electronic Structure of a Mononuclear Copper(II) Complex Supported by Tris(2-hydroxyliminopropyl)amine

Invited Article

Polyhedron, 2020, 177, 114306
48 Krzystek J, Schnegg A, Aliabadi A, Holldack K, Stoian SA, Ozarowski A, Hicks SD, Abu-Omar MM, Thomas KE, Ghosh A, Caulfield KP, Tonzetich JZ, Telser J Advanced Paramagnetic Resonance Studies on Manganese and Iron Corroles with a Formal d4 Electron Count Inorg. Chem., 2020, 59, 1075-1090
47 Dragulescu-Andrasi A, Filatov SA, Oakley RT, Li X, Lekin K, Huq A, Pak C, Greer SM, McKay J, Jo M, Lengyel J, Hung I, Maradzike E, DePrince E, Stoian SA, Hill S, Hu Y-Y, Shatruk S Radical Dimerization in Plastic Organic Crystal Leads to Structural and Magnetic Bistability with Wide Thermal Hysteresis J. Am. Chem. Soc., 2019, 141, 17989-17994
46 Grass A, Stoian SA, Lord RL, Groysman S Transition Metal-Mediated Reductive Coupling of Diazoesters Chem. Comm., 2019, 55, 8458-8461
45 Hamilton JAG, Ozarowski A, Archibong E, Thomas S, Serano-Garcia W, Stoian SA, Weider C, Mateeva N Synthesis and Characterization of Novel Polyethylene Oxide – Dinuclear Cu(II) Complex Electrospun Nanofibers Material Letters, 2019, 238, 58-61
44 Bindra JK, Kurian G, Christian JH, van Tol J, Singh K, Dalal NS, Mochena MD, Stoian SA, Strouse GF Evidence of Ferrimagnetism in Fe-Doped CdSe Quantum Dots Chem. Mater., 2018, 30, 8446-8456
43 Steele JL, Tahsini L, Chen S, Elinburg JK, Kotyk CM, McNeely J, Stoian SA, Andrasi DA, Ozarowski A, Ozerov M, Krzystek J, Telser J, Bacon JW, Golen JA, Rheingolde AL, Doerrer LH Square-planar Co(III) in {O4} coordination: large ZFS and reactivity with ROS Chem. Comm. , 2018, 54, 12045-12048
42 Kaniewska K, Dragulescu-Andrasi A, Ponikiewski L, Pikies J, Stoian SA, Grubba R Syntheses, structures and reactivity of terminal phosphido complexes of iron(II) supported by a β‐diketiminato ligand Eur. J. Inorg. Chem., 2018, 38, 4298-4308
41 Weeraratne ADKI, Baydoun H, Shakya R, Niklas J, Xie L, Mao G, Stoian SA, Poluektov OG, Verani CN Observation of Current Rectification by the New Bimetallic Iron(III) Hydrophobe [FeIII2(LN4O6)] on Au|LB-Molecule|Au Devices Dalton Trans., 2018, 47, 14352-14361
40 Brinzari TV, Rajan D, Ferreira CF, Stoian SA, Quintero PA, Meisel MW, Talham DR Light-Induced Magnetization Changes in Aggregated and Isolated Cobalt Ferrite Nanoparticles

Editor's Choice

J. Appl. Phys., 2018, 124, 103904
39 Yousif M, Wannipurage D, Huizenga CD, Washnock-Schmid E, Peraino NJ, Ozarowski A, Stoian SA, Lord RL, Groysman S Catalytic Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up the Alkoxide Enables a Wider Range of Substrates and Provides Insight into the Reaction Mechanism Inorg. Chem., 2018, 57, 9425-9438
38 Lengley J, Stoian SA, Dalal N, Shatruk M Directed Synthesis and Magnetic Properties of a Hexanuclear Ferric Cluster Polyhedron, 2018, 151, 446-451
37 Greer MG, McKay J, Graminga KM, Thomas CT, Stoian SA, Hill S Probing Fe–V Bonding in a C3-Symmetric Heterobimetallic Complex Inorg. Chem., 2018, 57, 5870-5878
36 Ferreira T, Carone D, Huon A, Herklotz A, Stoian SA, Heald SM, Morrison G, Smith MD, zur Loye H-C Ba3Fe1.56Ir1.44O9: A Polar Semiconducting Triple Perovskite with Near Room Temperature Magnetic Ordering Inorg. Chem., 2018, 57, 7632-7371
35 Yergeshbayeva S, Hrudka JJ, Lengyel J, Erkasov R, Stoian SA, Dragulescu-Andrasi A, Shatruk M Heteroleptic Fe(II) Complexes with N4S2 Coordination as a Platform for Designing Spin-Crossover Material Inorg. Chem., 2017, 56, 11096-11103
34 Grubba R, Kaniewska K, Ponikiewski Ł, Cristóvão B, Ferenc W, Dragulescu-Andrasi A, Krzystek J, Stoian SA, Pikies, J Synthetic, Structural and Spectroscopic Characterization of a Novel Family of Fe(II)-Phosphanylphosphido Complexes Inorg. Chem., 2017, 56, 11030-11042

Publications before joining U of I

33 Stoian SA, Peng YR, Beedle CB, Chung Y-J, Lee G-H, En-Che Y, Hill S Structural, Spectroscopic and Theoretical Investigation of a T-Shaped [Fe33-O)] Cluster Inorg. Chem., 2017, 56, 10861-10874
32 Zhang, M, Yang T, Wang Z, Ma X-F, Zhang Y, Greer SM, Stoian SA, Ouyang Z-W, Nojiri H, Kurmoo M, Zeng M-H Chemical Reaction within a Compact Non-Porous Crystal Containing Molecular Clusters without Lost of Crystallinity

Edge Article

Chem. Sci., 2017, 8, 5356-5361
31 Brozek CK, Ozarowski A, Stoian SA, Dinca M Dynamic Structural Flexibility of Fe-MOF-5 Evidenced by 57Fe Mössbauer Spectroscopy Inorg. Chem. Front., 2017, 4, 782-788
30 Reger DL, Pascui AE, Foley EA, Smith MD, Jezierska J, Wojciechowska A, Stoian SA, Ozarowski A, Dinuclear Metallacycles with Single M-X-M Bridges (X = Cl-, Br-; M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)): Strong Antiferromagnetic Superexchange Interactions Inorg. Chem., 2017, 56, 2884-2901
29 Latshaw AM, Chance WM, Morrison G, zur Loye KD, Wilkins BO, Smith MD, Whitfield PS, Kirkham MJ, Stoian SA, zur Loye H-C Synthesis of a Ferrolite: A Zeolitic All-Iron Framework

Hot Paper

Angew.Chem.Int.Ed., 2016, 55, 13195-13199
28 Arroyave A, Lennartson A, Dragulescu-Andrasi A, Pedersen KS, Piligkos S, Stoian SA, Greer SM, Hietsoi O, Phan H, Hill S, McKenzie CJ, Shatruk, M Spin Crossover in Fe(II) Complexes with N4S2 Coordination Inorg. Chem., 2016, 55, 5904-5913
27 Pascualini ME, Stoian, SA,Ozarowski, A, Abboud, KA, Veige, AS Solid State Collapse of a High-Spin Square-Planar Fe(II) Complex, Solution Phase Dynamics, and Electronic Structure Characterization of an Fe(II)2 Dimer Inorg. Chem., 2016, 55, 5191-5200
26 Bellow JA, Stoian SA, Van Tol J, Ozarowski A, Lord RL, Groysman S Synthesis and Characterization of A Stable High-Valent Cobalt Carbene Complex J. Am. Chem. Soc., 2016, 138, 5531-5534
25 Holmberg RJ, Burns T, Greer SG, Kobera L, Stoian SA, Korobkov I, Hill S, Bryce DL; Woo TK, Murugesu M Intercalation of Coordinatively Unsaturated FeIII Ion within Interpenetrated MOF-5 Chem. Eur. J., 2016, 22, 7711-7715
24 Pascualini M, Stoian SA, Ozarowski A, DiRusso N, Thuijs A, Khalil A, Christou G, Veige AS Synthesis and Characterization of a Family of M2+ Complexes Supported by a Trianionic ONO3- Pincer Ligand: Toward the Stabilization of High-Spin Square Planar Complexes Dalton Trans., 2015, 44, 20207-20215
23 Brozek CK, Miller TJ, Stoian SA, Dincă M NO Disproportionation at a Mononuclear Site-Isolated Fe2+ Center in Fe2+-MOF-5 J. Am. Chem. Soc., 2015, 137, 7495-7501
22 Reed BR, Stoian SA, Lord RL, Groysman S The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(I) complexes of a bis(aldimino)pyridine ligand

Inside Cover

Chem. Comm., 2015, 51, 6496-6499
21 Pascualini ME, Di Russo NV, Thuijs AE, Ozarowski A, Stoian SA, Abboud KA, Christou G, Veige AS A High-Spin Square Palanar Fe(II) Complex Stabilized by a Trianionic Pincer-Type Ligand and Conclusive Evidence for Retention of Geometry in Solution

Edge Article

Chem. Sci., 2015, 6, 608-612
20 Harriman KLM, Leitch AA, Stoian SA, Habib F, Kneebone JL, Gorelsky SI, Korobkov I, Desgreniers S, Neidig ML, Hill S, Murugesu M, Brusso Ambivalent binding between a radical-based pincer ligand and iron Dalton. Trans., 2015, 44, 10516-10523
19 Ping C, Stoian SA, Tan X, Dube PA, Shatruk M Investigation of Magnetic and Electronic Structure of Layered-Structure Borides AlT2B2 (T=Fe, Mn, Cr) and AlFe2-xMnxB2 J. Solid State Chem., 2015, 224, 52-61
18 Stoian SA, Xue G, Bominaar EL, Que Jr. L, Munck E Spectroscopic and Theoretical Investigation of a Complex with an [O=FeIV-O-FeIV=O] Core Related to Methane Monooxygenase Intermediate Q J. Am. Chem. Soc., 2014, 136, 1545-1558
17 Stoian SA, Hsieh CH, Singleton ML, Casuras AF, Darensbourg MY, McNeely K, Sweely K, Popescu CV Hyperfine interactions and electron distribution in Fe(II)Fe (I) and Fe (I)Fe (I) models for the active site of the [FeFe]-hydrogenases: Mössbauer spectroscopy studies of low-spin Fe(I) J. Biol. Inorg. Chem., 2013, 18, 609-622
16 Aukema KG, Makris TM, Stoian SA, Richman JE, Münck E, Lipscomb JD, Wackett LP Cyanobacterial Aldehyde Deformylase Oxygenation of Aldehydes Yields n – 1 Aldehydes and Alcohols in Addition to Alkanes ACS Catal., 2013, 3, 2228–2238
15 Dogutan D, Stoian SA, McGuire R, Schwalbe M, Teets T, Nocera DG Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry J. Am. Chem. Soc., 2011, 133,131-140
14 Schwalbe M, Dogutan D, Stoian SA, Teets T, Surendranath Y, Nocera DG Iron Xanthene-Modified and Hangman Corrole Inorg. Chem., 2011, 50, 1368-1377
13 McAlpin G, Surendranath Y, Dincă M, Stich TA, Stoian SA, Casey WH, Nocera DG, Britt RD EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH J. Am. Chem. Soc., 2010, 132, 6882-6883
12 Stoian SA, Paraschiv C, Kiritsakas N, Lloret F, Munck E, Bominaar EL, Andruh MC Mössbauer, EPR, and magnetic susceptibility studies on members of a new family of cyano-bridged 3d-4f complexes. Demonstration of anisotropic exchange in a Fe-Gd complex Inorg. Chem., 2010, 49, 3387-3401
11 Radosevich AT, Melnick JG, Stoian SA, Bacciu D, Chen C-H, Foxman BM, Ozerov OV, Nocera DG Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3 Inorg. Chem., 2009, 48, 9214-9221
10 Popescu CV, Mock MT, Stoian SA, Dougherty WG, Yap GPA, Riordan CG A High-Spin Organometallic Fe−S Compound: Structural and Mössbauer Spectroscopic Studies of [Phenyltris((tert-butylthio)methyl)borate]Fe(Me) Inorg. Chem., 2009, 48, 8317-8324
9 Stoian SA, Smith JM, Holland PL, Munck E, Bominaar EL Mössbauer, Electron Paramagnetic Resonance, and Theoretical Study of a High-Spin, Four-Coordinate Fe(II) Diketiminate Complex Inorg. Chem., 2008, 47, 8687–8695
8 Shatruk M, Dragulescu-Andrasi A, Chambers KE, Stoian SA, Bominaar EL, Achim C, Dunbar KR Properties of Prussian Blue Materials Manifested in Molecular Complexes: Observation of Cyanide Linkage Isomerism and Spin-Crossover Behavior in Pentanuclear Cyanide Clusters J. Am. Chem. Soc., 2007, 129, 6104–6116
7 Eckert NA, Vaddadi S, Stoian S, Lachicotte RJ, Cundari TR, Holland PL Coordination Number Dependence of Reactivity in an Imidoiron(III) Complex Angew. Chem. Int. Ed., 2006, 45, 6868-6871
6 Stoian SA, Vela J, Smith JM, Sadique AR, Holland PL, Munck E, Bominaar EL Mössbauer and Computational Study of an N2-Bridged Diiron Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen J. Am. Chem. Soc., 2006, 128, 10181-10192
5 Pestovsky O, Stoian S, Bominaar EL, Shan X, Munck E, Que Jr. L, Bakac A Aqueous FeIV=O: Spectroscopic identification and oxo-group exchange

Very Important Paper

Angew. Chem. Int. Ed., 2005, 44, 6871-6874
4 Benett MV, Stoian S, Bominaar EL, Munck E, Holm RH Initial Members of the Family of Molecular Mid-Valent High-Nuclearity Iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X=Cl-, Br-) J. Am. Chem. Soc., 2005, 127, 12378-12386
3 Stoian SA, Yu Y, Smith JM, Holland PL, Bominaar EL, Munck E Mössbauer, EPR and Crystallographic Characterization of a High-spin Fe(I) Diketiminate Complex with Orbital Degeneracy Inorg. Chem., 2005, 44, 4915-4922
2 Eckert NA, Stoian S, Smith JM, Lachicotte RJ, Bominaar EL, Munck E, Holland PL A Fully Reduced Oxodiiron(II) Complex J. Am. Chem. Soc., 2005, 127, 9344-9345
1 Vela J, Stoian S, Flaschenriem C, Münck E, Holland PL A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates J. Am. Chem. Soc., 2004, 126, 4522-4523